The CLQ and TLR of NH4+-N for PVL and PVGL were - 114.613 mg and - 63.43%, - 121.364 mg, and - 67.16%, respectively. Further, the addition of biochar as a modifier significantly slowed down the substrate layer TP leaching effect and improved the interception effect of NH4+-N and TN. Moreover, although polyacrylamide addition in the substrate layer aggravated the nitrogen leaching phenomenon in the EGRs' outflow, but the granular structure substrate layer constructed by it exhibited a significantly inhibited TP leaching effect.The partial or full replacement of natural aggregates with recycled ones can lessen the harmful effects of concrete industry on the environment. Despite offering sustainability benefits, recycled aggregate concrete (RAC) is inherently brittle under tension similar to natural aggregate concrete (NAC). The present study aimed to enhance the ductility of plain RAC by using hybrid fibers. The effect of single and hybrid fibers was studied on the flexural behavior (flexural strength, flexural toughness, residual strength), splitting tensile strength, and compressive strength of RAC. Polypropylene fiber (PPF) and hooked steel fiber (HSF) and hybrid fiber combination (0.85% HSF + 0.15% PPF) were used in RAC and NAC at a 1% volume fraction of concrete. The results showed that RAC with 1% PPF performed poorly compared to the RAC with 1% HSF. RAC incorporating 1% HSF or hybrid HSF-PPF fibers showed overall better performance than plain NAC. A substantial increment in the tensile and flexural strength of RAC was observed with the incorporation singular HSF and hybrid HSF-PPF. https://www.selleckchem.com/products/BEZ235.html Hybrid fibers have higher efficiency than singular HSF in both RAC and NAC. Residual strength, flexural strength, and flexural toughness of RAC with HSF and hybrid fibers were notably higher compared to the conventional plain NAC. The addition of 0.85% HSF + 0.15% PPF is beneficial to the imperviousness of concrete, and it reduced the water absorption capacity of RAC by 6.4%.This study revealed a dual pathway for the degradation of tris(1-chloro-2-propanyl) phosphate (TCPP) by zero-valent iron (ZVI) and persulfate as co-milling agents in a mechanochemical (MC) process. Persulfate was activated with ZVI to degrade TCPP in a planetary ball mill. After milling for 2 h, 96.5% of the TCPP was degraded with the release of 63.16, 50.39, and 42.01% of the Cl-, SO42-, and PO43-, respectively. In the first degradation pathway, persulfate was activated with ZVI to produce hydroxyl (·OH) radicals, and ZVI is oxidized to Fe(II) and Fe(III). A substitution reaction occurred as a result of the attack of ·OH on the P-O-C bonds, leading to the successive breakage of the three P-O-C bonds in TCPP to produce PO43-. In the second pathway, a C-Cl bond in part of the TCPP molecule was oxidized by SO4·- to carbonyl and carboxyl groups. The P-O-C bonds continued to react with ·OH to produce PO43-. Finally, the intermediate organochloride products were further reductively dechlorinated by ZVI. However, the synergistic effect of the oxidation (·OH and SO4·-) and the reduction reaction (ZVI) did not completely degrade TCPP to CO2, resulting in a low mineralization rate (35.87%). Moreover, the intermediate products still showed the toxicities in LD50 and developmental toxicant. In addition, the method was applied for the degradation of TCPP in soil, and high degradations (> 83.83%) were achieved in different types of soils.This study investigated the removal of an organic drug called ibuprofen from the wastewater containing this drug. Iron oxide supported on modified Iranian clinoptilolite was used as the photocatalyst in the presence of the light of a solar lamp. XRD, SEM, EDAX, and FT-IR analyses were performed to detect the prepared photocatalyst. The results of photocatalytic identification analyses proved the suitable loading of iron oxide supported on modified Iranian clinoptilolite. This study investigated the effect of initial concentration of ibuprofen (5-25 mg/L), photocatalyst concentration (100-300 mg/L), and process time (10-240 min) on the removal from ibuprofen from wastewater containing this drug. The experiments were performed in a setup in the presence of a solar lamp with a flux of 300 W/m2. The results indicated that with the initial ibuprofen concentration of 25 mg/L, photocatalyst concentration of 300 mg/L, and time of 210 min, the highest percentage of ibuprofen removal and ibuprofen adsorbed on the catalyst were 99.80% and 83.17 mg/g, respectively. Kinetic modeling was then performed using the Langmuir-Hinshelwood model, and a quasi-first-order kinetic model showed a good agreement with the results obtained. Finally, the recovery of the photocatalyst was investigated, and the results showed that under optimal conditions about 91% of ibuprofen was removed after five re-uses of the photocatalyst.Semiconductor photocatalysis technology has shown great potential in the field of organic pollutant removal, as it can use clean and pollution-free solar energy as driving force. The discovery of silver phosphate (Ag3PO4) is a major breakthrough in the field of visible light responsive semiconductor photocatalysis due to its robust capacity to absorb visible light  less then  520 nm. Furthermore, the holes produced in Ag3PO4 under light excitation possess a strong oxidation ability. However, the strong oxidation activity of Ag3PO4 is only achieved in the presence of electron sacrifice agents. Otherwise, photocorrosion would greatly reduce the reuse efficiency of Ag3PO4. This review thus focuses on the structural characteristics and preparation methods of Ag3PO4. Particularly, the recent advances in noble metal deposition, ion doping, and semiconductor coupling, as well as methods of magnetic composite modification for the improvement of catalytic activity and recycling efficiency of Ag3PO4-based catalysts, were also discussed, and all of these measures could enhance the catalytic performance of Ag3PO4 toward organic pollutants degradation. Additionally, some potential modification methods for Ag3PO4 were also proposed. This review thus provides insights into the advantages and disadvantages of the application of Ag3PO4 in the field of photocatalysis, clarifies the photocorrosion essence of Ag3PO4, and reveals the means to improve photocatalytic activity and stability of Ag3PO4. Furthermore, it provides a theoretical and methodological basis for studying Ag3PO4-based photocatalyst and also compiles valuable information regarding the photocatalytic treatment of organic polluted wastewater.The present study, with the aid of GIS, utilizes high-density groundwater (GW) sampling data (1398 samples) to analyze the spatial variation characteristics of GW fluoride in Weifang City (WFC), and evaluate the health risks associated with drinking water routes. The concentration of fluoride in the GW of WFC is observed to be between 0.08 and 9.16 mg/L, with a mean value of 0.62 mg/L. The fluoride concentration of a total of 192 GW samples exceeded the limit of China's GW quality standards (1 mg/L), accounting for 14.74%. The GW fluoride concentration in most areas of WFC is less than 1 mg/L. However, the relatively high-value zones are mostly concentrated in the upper reaches of Wen River, the east of Shouguang, the southeast of Anqiu, the east of Qingzhou, the east of Fangzi, and the southeast and northwest of Gaomi. The hydrochemical types of GW in WFC are mostly HCO3-Ca·Mg and SO4·Cl-Ca·Mg, while GW samples with hydrochemical types HCO3-Na and SO4·Cl-Na are characterized by high fluoride content. The hydrochemical characteristics of GW in WFC are mostly dominated by rock weathering. In addition, the northern coastal plain is evidently influenced by seawater intrusion. The concentration of fluoride in GW is affected by the dissolution of fluorine-containing minerals, cation exchange, and alkaline environmental factors. The effect of GW by seawater intrusion and very high content of Na+ will decrease the fluoride content of the GW through cation exchange. Health risk assessment demonstrated that the mean values of non-carcinogenic hazard quotient (HQ) for infants, children, teenagers, and adults were 0.52, 0.35, 0.31, and 0.30, respectively. In addition, the distribution characteristics of GW fluoride in high health risk areas (HQ > 1) in WFC are further consistent with the spatial variation of GW fluoride content. Overall, the health risk distribution area of GW fluoride in WFC is decreasing in the following order infants > children > teenagers > adults.The increase in average annual temperature due to greenhouse gases emission is posing threat to the agriculture sector across the globe. Pakistan is labor abundant agrarian country that heavily depends on the agriculture sector for food, employment, and raw material for industries. This study is a preliminary investigation that explores the effect of increasing average annual temperature on the competitiveness of 24 major agricultural exports from 2003 to 2020. The revealed export advantage (RXA) is used to explore the competitive performance of selected agricultural exports, which is then normalized to examine the effect of increasing average annual temperature along with official exchange rate, urbanization, and globalization. The panel fixed-effect model with heteroscedasticity consistent robust standard error recommended by White (Econometrica 48(4)817-838, 1980) is used to explore model estimates, whereas the robustness check has been performed by using heteroscedasticity and multicollinearity consistent robust standard error model of Driscoll and Kaary (Rev Econ Stat 80(4)549-559, 1998). The estimated result reveals that the increasing average annual temperature has a negative but insignificant impact on the export competitiveness of selected agricultural exports. While, urbanization and exchange rate deprecation show a significant negative effect of higher intensity, respectively. Globalization, however, reveals a significant positive impact on the competitiveness of selected agricultural exports. This study, therefore, urges for the development of the agriculture sector by adopting SDGs proposed by the United Nations for sustainable economic growth and development.This study investigates the effect of China's national Five-Year Plan for environmental protection (FYPEP) on corporate green innovations based on the two-way fixed effect model and panel data about the green patents of China's publicly listed corporations during 1990-2020. Furthermore, the heterogeneity of these green innovations is further discussed with reference to the types of innovation, enterprise ownership, and the location of the corporations. It is found that FYPEP significantly induced corporation green innovations at regional and industrial levels. Heterogeneity analysis indicates that the inductive effect of FYPEP is stronger on green utility model patents than on green invention patents. State-owned enterprises react to green innovation policies more significantly than do private businesses. The inductive effect of FYPEP is stronger in Eastern China than in mid- and Western China. From the perspective of government intervention, this research renders a new framework for the formulation of policies of national environmental protection and corporate green innovation.