10/14/2024


ies with lower SEP. Earlier warnings regarding extreme heat are recommended to decrease pregnancy complications.Floating treatment wetlands (FTWs) are increasingly gaining popularity due to a set of valuable features like wastewater remediation under varied conditions, ecosystem quality preservation, landscape conservation, and aesthetic benefits. FTW is a phyto-technology in which macrophytes grow on a floating raft with their roots in permanent contact with water and remove pollutants via several physicochemical-biological processes. FTW is highly capable of overcoming technical and operational challenges that come way in stormwater treatment due to the erratic nature of hydrologic and input pollutant loads because this innovative buoyant hydroponic design can move up and down with fluctuating water levels in the stormwater pond and can treat highly variable flows. Plants and biofilms attached to the roots hanging beneath the floating mat play a pivotal role in FTWs. The present review encompasses the concept of FTWs, their structural designs, relevance in stormwater management, and mechanism of plant uptake for pollutant removal. The role of FTWs to remove heavy metals and nutrients is also critically analyzed. Understanding hydraulics and other parameters of FTW is vital to effective design. Hence, the role of vegetation coverage, vegetation type, sorption media, aeration frequency, and intensity, and plant density to enhance system efficiency is also highlighted. Due to their operational flexibility and environmentally friendly working with no additional burden on existing urban land use, FTWs entice broad international interest and offer a coherent solution for stormwater management. https://www.selleckchem.com/products/beta-aminopropionitrile.html MAIN FINDINGS The review delivers state-of-the-art analysis of the current understanding of hydraulics and other parameters of FTWs, and associated mechanisms to enhance the treatment efficiency of FTWs for nutrients and heavy metals removal.Powdered activated carbon (PAC) is a strong adsorbent also capable of catalyzing ozonation processes. Ozone (O3) and PAC were simultaneously applied to treat a mixture of 17 micropollutants (MPs) at low concentrations, including 13 compounds that were studied for the first time by simultaneous addition of O3 and PAC system. Synergy and catalysis improved the removals and specific degradation rates of MPs in the first minute of the treatment. Radical probing experiments showed that scavenging hydroxyl radicals (OH) did not have a significant impact on the removals, while scavenging other reactive oxygen species was more influential. A detailed study by electron paramagnetic resonance spectroscopy ascertained that the decomposition of ozone in presence of PAC at neutral pH did not boost the generation of free OH. Instead, adsorbed OH was likely produced as PAC-HO along with other oxidizing species resulting from adsorbed singlet oxygen and superoxide radicals.The coupling transformation of carbon, nitrogen and sulfur compounds has been studied in lab-scale and pilot-scale constructed wetlands (CWs), but few studies investigated full-scale CW. In this study, we used batch experiments to investigate the potentials of carbon, nitrogen and sulfur transformation in a long-term operated, full-scale horizontal subsurface flow wetland. The sediments collected from the HSFW were incubated for 48 h in the laboratory with supplying various dosages of carbon, nitrogen and sulfur compounds. The results showed that heterotrophic denitrification was the main pathway. At the same time, the sulfide (S2-)-based autotrophic denitrification was also present. Increasing TOC concentration or NO3- concentration could promote heterotrophic denitrification but did not inhibit the sulfide-based autotrophic denitrification. In our experiment, the highest NO3- removal via autotrophic denitrification was 25.23% while that via heterotrophic denitrification was 73.66%, leading to the total NO3- removal of 98.89%. The results also demonstrated that NO3- rather than NO2- was the preferable electron acceptor for both heterotrophic and sulfide-based autotrophic denitrification in the CW. Increasing S2- concentrations promote NO3- removal from 12.99% to 25.23% without organic carbon, but varying NO3- or NO2- has no effects. These results indicated that concentrations of S2-, instead of NO3- or NO2-, was the limiting factor for sulfide-based autotrophic denitrification in the studied CW. The microbial community analysis and correlation analysis between the transformation of carbon, nitrogen and sulfur compounds and relative abundance of bacteria further confirmed that in the CW, the key pathways coupling transformation were heterotrophic denitrification and sulfide-based autotrophic denitrification. Overall, the current study will enhance understanding of carbon, nitrogen, and sulfur transformation in CW and support better design and treatment efficiency.Large amounts of antibiotics from different sources have been released into coastal environments, especially in high human-populated areas, but comprehensive studies of antibiotic footprint in wildlife are scarce. Here we assess occurrence of antibiotic resistant bacteria (ARB) and antibiotic resistance gene (ARG) both in sediments and gut microbiota of a long-distance migratory shorebird species in two coastal wetlands at a sparsely-populated area in Pacific Patagonian coasts with contrasting potential antibiotic sources, especially from aquaculture. We found 62% of sediment samples showing ARB, and ARGs similarly occurring in sediments at both bays. However multi-resistant ARB were found only at sediments in the bay surrounding aquaculture operations. An 87% of cloacal bird samples showed at least one ARB, with 63% being multi-resistant and some of them with a high potential pathogenicity. ARGs were present in 46% of the samples from birds, with similar multi-resistant frequencies among bays. Besides specific differences mainly associated to antibiotics used in salmon aquaculture that boosted ARB in sediments, ARB and ARGs occurrence was overall similar at two bays with contrasting main human activities, in spite of being a comparatively low human-populated area. Therefore, our results reinforce the idea that the antibiotic footprint may be widespread at a global scale and can extend beyond the geographical influence of antibiotic sources, especially at coastal environments where migratory shorebirds act both as reservoirs and potential spreaders of antibiotic resistance.