We show that, in the NVT ensemble, it is possible to equilibrate and stabilise critical bubbles for a long time. The nucleation rate inferred from NVT-Seeding is fully consistent with that coming from NPT-Seeding. The former is quite suitable to obtain the nucleation rate along isotherms, whereas the latter is preferable if the dependence of the rate with temperature at constant pressure is required. Care should be taken with finite size effects when using NVT-Seeding. Further work is required to extend NVT seeding to other sorts of phase transitions.A Hamiltonian-based model of many harmonically interacting massive particles that are subject to linear friction and coupled to heat baths at different temperatures is used to study the dynamic approach to equilibrium and nonequilibrium stationary states. An equilibrium system is here defined as a system whose stationary distribution equals the Boltzmann distribution, the relation of this definition to the conditions of detailed balance and vanishing probability current is discussed both for underdamped as well as for overdamped systems. Based on the exactly calculated dynamic approach to the stationary distribution, the functional that governs this approach, which is called the free entropy S_free(t), is constructed. For the stationary distribution S_free(t) becomes maximal and its time derivative, the free entropy production S[over ̇]_free(t), is minimal and vanishes. Thus, S_free(t) characterizes equilibrium as well as nonequilibrium stationary distributions by their extremal and stability propertirature of the heat bath it is coupled to. Active particle models can be described in the same general framework, which thereby allows us to characterize their entropy production not only in the stationary state but also in the approach to the stationary nonequilibrium state. Finally, the connection to nonequilibrium thermodynamics formulations that include the reservoir entropy production is discussed.The geomagnetic field's dipole undergoes polarity reversals in irregular time intervals. Particularly long periods without reversals (of the order of 10^7 yr), called superchrons, have occurred at least three times in the Phanerozoic (since 541 million years ago). We provide observational evidence for high non-Gaussianity in the vicinity of a transition to and from a geomagnetic superchron, consisting of a sharp increase in high-order moments (skewness and kurtosis) of the dipole's distribution. Such an increase in the moments is a universal feature of crisis-induced intermittency in low-dimensional dynamical systems undergoing global bifurcations. This implies a temporal variation of the underlying parameters of the physical system. Through a low-dimensional system that models the geomagnetic reversals, we show that the increase in the high-order moments during transitions to geomagnetic superchrons is caused by the progressive destruction of global periodic orbits exhibiting both polarities as the system approaches a merging bifurcation. We argue that the non-Gaussianity in this system is caused by the redistribution of the attractor around local cycles as global ones are destroyed.Collective decision making processes lie at the heart of many social, political, and economic challenges. The classical voter model is a well-established conceptual model to study such processes. In this work, we define a form of adaptive (or coevolutionary) voter model posed on a simplicial complex, i.e., on a certain class of hypernetworks or hypergraphs. We use the persuasion rule along edges of the classical voter model and the recently studied rewiring rule of edges towards like-minded nodes, and introduce a peer-pressure rule applied to three nodes connected via a 2-simplex. This simplicial adaptive voter model is studied via numerical simulation. We show that adding the effect of peer pressure to an adaptive voter model leaves its fragmentation transition, i.e., the transition upon varying the rewiring rate from a single majority state into a fragmented state of two different opinion subgraphs, intact. Yet, above and below the fragmentation transition, we observe that the peer pressure has substantial quantitative effects. It accelerates the transition to a single-opinion state below the transition and also speeds up the system dynamics towards fragmentation above the transition. Furthermore, we quantify that there is a multiscale hierarchy in the model leading to the depletion of 2-simplices, before the depletion of active edges. This leads to the conjecture that many other dynamic network models on simplicial complexes may show a similar behavior with respect to the sequential evolution of simplices of different dimensions.Starting from the stochastic thermodynamics description of two coupled underdamped Brownian particles, we showcase and compare three different coarse-graining schemes leading to an effective thermodynamic description for the first of the two particles marginalization over one particle, bipartite structure with information flows, and the Hamiltonian of mean force formalism. In the limit of time-scale separation where the second particle with a fast relaxation time scale locally equilibrates with respect to the coordinates of the first slowly relaxing particle, the effective thermodynamics resulting from the first and third approach are shown to capture the full thermodynamics and to coincide with each other. In the bipartite approach, the slow part does not, in general, allow for an exact thermodynamic description as the entropic exchange between the particles is ignored. Physically, the second particle effectively becomes part of the heat reservoir. In the limit where the second particle becomes heavy and thus deterministic, the effective thermodynamics of the first two coarse-graining methods coincide with the full one. https://www.selleckchem.com/products/jw74.html The Hamiltonian of mean force formalism, however, is shown to be incompatible with that limit. Physically, the second particle becomes a work source. These theoretical results are illustrated using an exactly solvable harmonic model.We compare two formulas obtained from first principles to calculate the electron-ion coupling factor for temperature relaxation in dense plasmas. The quantum average-atom model is used to calculate this electron-ion coupling factor. It is shown that if the two formulas agree at sufficiently high temperature so that the potential energy is of limited importance, i.e., when the plasma is said to be kinetic, and are consistent with the Landau-Spitzer formula, then they strongly differ in the warm-dense-matter regime. Only one of the two is shown to be consistent with quantum molecular dynamics approach. We use this point to determine which formula is valid to describe temperature relaxation between electrons and ions in warm and hot dense plasmas.